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stereoselectivity

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stereochemistry chirality enantiomer diastereomer isomer enantioselectivity diastereoselectivity catalyst enzyme substrate product reaction mechanism asymmetry chiral achiral racemate racemization epimer configuration conformation stereocenter stereogenic prochirality regioselectivity chemoselectivity selectivity yield excess purity resolution ligand transition state activation energy kinetics thermodynamics equilibrium induction auxiliary organocatalysis biocatalysis synthone synthon stereoisomer optical activity polarimetry rotation levorotatory dextrorotatory meso compound cis trans syn anti facial enantiomeric excess stereospecificity stereospecific stereoselective asymmetric synthesis chiral pool catalytic cycle coordination geometry hybridization orbital steric hindrance sterics electronics electrophile nucleophile reagent solvent temperature pressure concentration rate constant activation barrier transition state theory

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